部门

应用化学教研室

出生年月

1985.8

籍贯

黑龙江·北安

职称

副教授

邮箱

zhangjin@sust.edu.cn

电话

13474365549

研究方向

有机合成新反应和新方法、氮杂环卡宾、机械化学、惰性化学键活化

简  介

张金，理学博士，副教授、硕士生导师，中国化学会会员。现任化学与化工学院应用化学教研室副主任。

2003年至2007年，西北大学化学系应用化学专业本科，获理学学士学位；

2007年至2012年，西北大学化学系有机化学专业硕博连读，获理学博士学位（导师史真教授，李剑利教授）研究方向仿生有机合成新反应及方法学研究；同年赴陕西科技大学化学与化工学院任教。

2013年至2016年，陕西科技大学化学与化工学院化学工程与技术博士后流动站合作研究（合作导师：马养民教授），主要从事杂环化合物的设计合成与生物应用研究。

2018年至2019年，美国罗格斯大学-纽瓦克分校Michal Szostak教授课题组访问学者

主要研究方向：有机合成新反应和新方法、氮杂环卡宾、机械化学、惰性化学键活化研究。

主持研究项目：国家自然基金面上项目、陕西省自然科学基础研究计划项目、陕西省教育厅自然科学基金专项、陕西科技大学科研启动基金。

近年来，先后在Chemical Reviews、Angewandte Chemie International Edition、ACS Catalysis、Organic Letters、Chemical Communications、Journal of Organic Chemistry、European Journal of Organic Chemistry、Tetrahedron、Tetrahedron Letters、Bioorganic & Medicinal Chemistry Letters、高等学校化学学报、有机化学等国内外权威学术期刊发表研究论文，授权多项国家发明专利。

欢迎对科学研究有浓厚兴趣的同学报考本课题组硕士研究生！也欢迎喜欢科研的本科生加入课题组！

课题组主页：https://www.x-mol.com/groups/ZHANG_Jin-SUST

近期代表性论文：

24. Li Guangchen^#, Xing Yangyang^#, Zhao Hui^#, Zhang Jin*, Hong Xin*, Szostak Michal*, Chemoselective Transamidation of Thioamides by Transition-Metal-Free N–C(S) Transacylation, Angewandte Chmie, International Edition, 2022, 10.1002/anie.202200144.

23. Zhang Jin^*; Zhang Pei; Shao Lei; Wang Ruihong; Ma Yangmin; Szostak Michal,^* Mechanochemical Solvent-Free Suzuki-Miyaura Cross-Coupling of Amides via Highly Chemoselective N-C Cleavage, Angewandte Chemie, International Edition, 2022, 61(7), e202114146.

22. Meng Guangrong^#; Zhang Jin^#; Szostak Michal,^* Acyclic Twisted Amides, Chemical Reviews 2021, 121(20), 12746-12783.

21. Zhang Jin;^* Liu Zhulin; Yin Zheng; Yang Xiufang; Ma Yangmin; Szostak Roman; Szostak, Michal,* Preference of cis-Thioamide Structure in N-Thioacyl-N-methylanilines, Organic Letters, 2020, 22(24), 9500-9505.

20. Zhang Jin*, Liu Ying, Jia Qiangqiang, Wang Yue, Ma Yangmin, Szostak Michal,* Ruthenium(II)-Catalyzed C-H Arylation of N,N-Dialkyl Thiobenzamides with Boronic Acids by Sulfur Coordination in 2-MeTHF. Organic Letters, 2020, 22(17), 6884-6890.

19. Wang Xiaogang^#, Zhang Jin^#,*, He Yuan, Chen Di, Wang Chao, Yang Fangzhou, Wang Weitao, Ma Yangmin*, Szostak Michal*, Ruthenium(II)-Catalyzed Ortho-C-H Alkylation of Naphthylamines with Diazo Compounds for Synthesis of 2,2-Disubstituted π-Extended 3-Oxindoles in Water. Organic Letters, 2020, 22(13), 5187-5192. (共同一作)

18. Zhang Jin*, Wang Xiaogang, Chen Di, Kang Yifan, Ma Yangmin*, Szostak Michal*, Synthesis of C6-Substituted Isoquinolino[1,2-b]quinazolines via Rh(III)-Catalyzed C–H Annulation with Sulfoxonium Ylides. Journal of Organic Chemistry, 2020, 85(5), 3192-3201.

17. Zhang Jin*, Zhuang Yuyu, Ma Yangmin, Yang Xiufang*, and Szostak Michal*, Palladium-Catalyzed Synthesis of Benzothiophenes via Cross- Dehydrogenative Coupling of 4-Arylthiocoumarins and Pyrones. Advanced. Synthesis &. Catalysis. 2019, 361, 5709-5714.

16. Li Quan-Quan, He Peng-Xiu, Zhang Jin, Zhang Ji-Dong, Xin Yu-Meng, Liu Ping^*, Wang, Yao-Yu Li Jian-Li^*, Substituent changes in the salen ligands of CuIINaI-complexes to induce various structures and catalytic activities towards 2-imidazolines from nitriles and 1,2-diaminopropane, Chemical Communications, 2019, 55(32), 4619-4622.

15. Wang Xiaogang^#, Zhang Jin^#,*, Chen Di, Wang Bo, Yang Xiufang, Ma Yangmin*, Szostak Michal*, Rh(III)-Catalyzed C–H Amidation of 2-Arylindoles with Dioxazolones: A Route to Indolo[1,2-c]quinazolines, Organic Letters, 2019, 21(17), 7038-7043.(共同一作)

14. Zhao Qun, Zhang Jin, Szostak Michal^*, Ruthenium(0)-sequential catalysis for the synthesis of sterically hindered amines by C–H arylation/hydrosilylation, Chemical Communications, 2019, 55, 9003-9006.

13. Zhao Qun, Zhang Jin, Szostak Michal^*, Ruthenium(0)-Catalyzed Cross-Coupling of Anilines with Organoboranes by Selective Carbon–Nitrogen Cleavage, ACS Catalysis, 2019, 9(9), 8171-8177.

12. Zhang Jin ^*, Hou Yanyan, Ma Yangmin^*, Szostak Michal^*, Synthesis of Amides by Mild Palladium-Catalyzed Aminocarbonylation of Arylsilanes with Amines Enabled by Copper(II) Fluoride, Journal of Organic Chemistry, 2019, 84(1), 338-345.

11. 张 金^*，史天彩，罗力文，刘 佳，刘 荣，刘 乐，梁 明，马养民^*，纳米氧化铜催化一锅法合成β⁃咔啉类化合物，高等学校化学学报，2018，39(11)：2411-2418.

10. Zhang Jin^*; Ma Yuqiang; Ma Yangmin^*, Synthesis of Secondary Amides through Palladium(II)-catalyzed Aminocarbonylation of Arylboronic Acids with Amines / Hydrazines and CO, European Journal of Organic Chemistry, 2018, 1720-1725.

9. 张金，刘佳，马养民^*，程佩，纳米金属氧化物催化含氮杂环类化合物的合成研究进展，有机化学，2017, 37(3): 555-565.

8. Zhang Jin, Cheng Pei, Ma Yangmin^*, Liu Jia, Miao Zhi, Ren Decheng, Fan Chao, Liang Ming, Liu Le. An efficient nano CuO-catalyzed synthesis and biological evaluation of quinazolinone Schiff base derivatives and bis-2, 3-dihydroquinazolin-4(1H)-ones as potent antibacterial agents against Streptococcus lactis. Tetrahedron Letters, 2016, 57(47), 5271-5277.

7. Zhang, Jin; Liu, Jia; Ma, Yangmin^*; Yang, Xiufang; Cheng, Pei; Fan, Chao; Lu, Ping. TiO₂ nanoparticles- catalyzed one-pot synthesis of quinazolino [2,1-b] phthalazin-8-one and 3-acylamino isoindolo [2,1-a] quinazoline derivatives. Gaodeng Xuexiao Huaxue Xuebao, 2016, 37(9), 1629-1635.

6. Zhang, Jin; Cheng, Pei; Ma, Yangmin^*; Liu, Jia; Miao, Zhi; Fan, Chao. Ultrasonic synthesis and anti-phytopathogenic fungi activity evaluation of 2-sulfanylidene-2,3-dihydroquinazoline-4(1H)-one. Youji Huaxue, 2016, 36(6), 1368-1374.

5. Zhang, Jin; Liu, Jia; Ma, Yangmin^*; Ren, Decheng; Cheng, Pei; Zhao, Jiawen; Zhang, Fan; Yao, Yuan. One-pot synthesis and antifungal activity against plant pathogens of quinazolinone derivatives containing an amide moiety. Bioorganic & Medicinal Chemistry Letters, 2016, 26(9), 2273-2277.

4. Zhang, Jin; Zhao, Jiawen; Wang, Liangpeng; Liu, Jia; Ren, Decheng; Ma, Yangmin. Design, synthesis and docking studies of some spiro-oxindole dihydroquinazolinones as antibacterial agents Tetrahedron, 2016, 72(7), 936-943.

3. Ma, Yangmin; Ren, Decheng; Zhang, Jin^*; Liu, Jia; Zhao, Jiawen; Wang, Liangpeng; Zhang, Fan. Synthesis, antibacterial activities evaluation, and docking studies of some 2-substituted-3- (phenylamino)-dihydroquinazolin-4(1H)-ones. Tetrahedron Letters, 2015, 56(27), 4076-4079.

2. Zhang, Jin^*; Ren, Decheng; Ma, Yangmin^*; Wang, Weitao; Wu, Hao. CuO nanoparticles catalyzed simple and efficient synthesis of 2,3-dihydroquinazolin-4(1H)-ones and quinazolin-4(3H)-ones under ultrasound irradiation in aqueous ethanol. Tetrahedron, 2014, 70(34), 5274-5282.

1. Zhang, Jin; Wang, Xiao; Yang, Meipan; Wan, Kerou; Yin, Bing; Wang, Yunxia; Li, Jianli^*; Shi, Zhen. Copper-catalyzed synthesis of 2-imidazolines and their N-hydroxyethyl derivatives under various conditions. Tetrahedron Letters, 2011, 52(14), 1578-1582.