承担 的主 要项 目及 成果 |
主要成果: (1) Bo Wang, Nan Liu, Wenwen Chen, Dayun Huang, Xinyan Wang, and Yuefei Hu*, Minutes synthesis of 1,4,5-trisubstituted 5-dialkylamino-1,2,3- triazoles by 1-copper(I)-alkyne controlled tandem process, Adv. Synth. Catal., 2015, 357, 401-407. (2) Bo Wang, Nan Liu, Changwei Shao and Yuefei Hu*. Preparation of 1,4,5-trisubstituted 5-acyl-1,2,3-triazoles by selective acylation between copper(I)-carbon(sp) and copper(I)-carbon (sp2) bonds with acyl chlorides. Adv. Synth. Catal., 2013, 355: 2564-2568. (3) Bo Wang, Jianlan Zhang, Xinyan Wang, Nan Liu, Wenwen Chen, and Yuefei Hu*, Tandem reaction of 1 copper(I) alkynes for the synthesis of 1,4,5-trisubstituted 5 chloro-1,2,3-triazoles, J. Org. Chem., 2013, 78, 10519-10523. (4) Bo Wang, Xinyan Wang, Yuefei Hu*, Easy preparation of 1,4,5-trisubstituted 5-(2-alkoxy-1,2-dioxoethyl)-1,2,3-triazoles by chemoselective trapping of copper(I)–carbon bond with alkoxalyl chloride, Tetrahedron Lett., 2013, 54, 6097-6100. (5) Bo Wang, Shihua Wang, Pinhua Li, Lei Wang*, Iron-catalyzed regio- and stereoselective addition of acid chlorides to alkynes. Chem. Commun., 2010, 46, 5891-5893. |